Acta Chimica Slovaca (ACS) publishes papers on fundamental and applied aspects of chemistry, biochemistry, chemical technology, chemical engineering and process control, biotechnology and food technology. Welcome are also topics which include chemical aspects of materials, physical chemistry and chemical physics, analytical chemistry, macromolecular chemistry and biomedical engineering.

Crystallosolvate Formation in Copper(II) 4-Nitrobenzoate Complex Systems

Jana Medvecká, Ján Moncoľ, Vladimír Jorík, Dušan Valigura *

Institute of Inorganic Chemistry, Technology and Materials, Faculty of Chemical and Food Technology STU, Radlinského 9, 812 37 Bratislava

E-mail: *

Abstract: Three different products [Cu2(4-NO2bz)4(denia)]∙(TOL) (1), [Cu2(4-NO2bz)4(EtOH)2] (2), and [Cu2(4-NO2bz)4(H2O)(AC)] (3) were obtained by the reaction of copper(II) acetate, N,N-diethylnicotinamide and 4-nitrobenzoic acid in different solvents. Complexes under study were characterized by elemental analysis and by IR, EPR or UV/VIS spectra. X-ray powder diffraction pattern were obtained to characterize samples and to compare obtained products with known ones.

Keywords: copper complexes, diethylnicotinamide, 4-nitrobenzoate, crystallosolvate

Full paper in Portable Document Format: acs_0059.pdf

Acta Chimica Slovaca, Vol. 3, No. 1, 2010, pp. 73—80