Structure of cis-dichlorobis(1,10-phenanthroline)manganese(II) and cis-dichlorobis(2,2'-bipyridine)manganese(II)
Faculty of Chemical and Food Technology, Slovak Technical University, Radlinského 9, SK-812 37, Bratislava, Slovakia
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Abstract: The crystal structures of the title compounds, [Mn(phen)2Cl2] (I) and [Mn(bipy)2Cl2] (II), have been determined at 150 K. The manganese atoms in both compounds are coordinated by four pyridine nitrogen atoms from two 1,10-phenanthroline or 4,4;-bipyridine ligands and two chloride anions, resulting in a distorted cis-MnN4Cl2 octahedral geometry. Both complexes are connected through C–H···Cl hydrogen bonds into frameworks. The π-π stacking interactions are observed in crystal structure of both ones.
Keywords: , X-ray, crystal structure, 1,10-phenanthroline, 4,4'-bipyridine
Full paper in Portable Document Format: acs_0179.pdf
Acta Chimica Slovaca, Vol. 7, No. 1, 2014, pp. 15—19, DOI: 10.2478/acs-2014-0003